Deaerator working principle, Types and Process Control, Types of Check Valves (Non Return Valve) NRV, Control Valve working, Components & Types, Distributed Control Systems (DCS) Information. \end{align}. The grey pig iron (“cast pig iron”) serves as a raw material for foundries to produce various types of cast iron or cast iron materials. Refractory lining of blast furnace A modern blast furnace (BF) is refractory lined to protect the furnace shell from the high temperatures and abrasive materials inside the furnace. With a daily production of 10,000 tons, this results in a coke input of 3,500 tons per day! The Cowper on August 5th has been set and put on heating up. The carbon dioxide gas (\(CO_2\)) reacts with the carbon contained in the coke (\(C\)) due to the very high temperatures and forms the carbon monoxide gas (\(CO\)) as the reducing agent: \begin{align} 4. Fe_3O_4 &~+~ CO &&\rightarrow~ 3~FeO &&+ ~CO_2 ~~~~~~ \text{(magnetite} \rightarrow \text{wüstite)} \\[5px] Required fields are marked *. The equilibrium then shifts in the direction of the condensation process (this effect can also be seen very clearly on cooled beverage cans, where the water contained in the air condenses and water pearls form). The direct reduction can again be divided into intermediate steps in which the iron content in the ores increases in each case: \begin{align} This leads to a temperature increase of up to 2000 °C. blast furnaces no.1 & 2, thyssenKrupp csa siderúrgica do atlântico, brazil. Published July 11, 2020, It’s hard to find knowledgeable folks on this topic, however you sound like you understand what you’re speaking about! Amongst all the ironmaking processes, the Blast Furnace technology, which has been around the longest, still holds the dominant position. Due to the direct reduction of iron oxides by carbon, one also speaks of a direct reduction. Too low a temperature would again mean the back reaction (indicated by the double arrow in the chemical equation) of the carbon monoxide to carbon dioxide. This combustion is very strongly exothermic, i.e. This is the reason why pig iron has a relatively high carbon content. At low temperatures, carbon monoxide mainly decomposes to carbon dioxide and carbon! However, the BF process relies heavily on metallurgical coke and involves cokemaking and sintering operations, which often attract serious environmental concerns. At high temperatures, carbon reacts predominantly with carbon dioxide to form carbon monoxide (as an important reducing agent). 3. In the blast furnace there are more monolithic refractory products in continuous operation than at any other stage in the steel production process - excluding new linings and interim repairs. Due to the higher density of the pig iron, the pig iron can be cut off at the lowest point of the blast furnace (called tapping). The refractory lining is cooled to further enhance the protection against the dispatch … How important is the “Boudouard reaction” for the blast furnace process? The unmelted iron ores still contain non-reduced iron oxides. This article provides answers to the following questions, among others: The iron in the processed ores must be dissolved out by chemical processes. The iron ore is dressed or crushed into 0.5-1 in. Metallurgy of the Blast Furnace. Blast Furnace Productivity Criteria. Graphite formation is also favoured by a relatively low manganese content and slow cooling. The project realized in August, during capital repair of blast furnace № 5 NLMK, included full service range, from the cleaning of collapsed brick lining until the restoration of protecting layer on the wall and pipe valves by gunning. The corresponding chemical reactions are as follows: \begin{align} Lining thickness be obtained from registration re-sult and is illustrated in Sec. ing points taking from the specific geometry of the blast . The Blast Furnace is a members-only minigame situated in Keldagrim for smelting bars.The furnace here only requires half as much coal when smelting usually, so it can be useful when smelting the ores that require more coal.. This type of solidification is therefore also referred to as stable solidification. The chemical processes are discussed in more detail in the chapter on blast furnace processes. In both cases the iron oxide is reduced to iron. 2018 Blast Furnace Inner Lining Maintenance Use Gunning Material , Find Complete Details about 2018 Blast Furnace Inner Lining Maintenance Use Gunning Material,Blast Furnace Gunning Material from Supplier or Manufacturer-Zhengzhou Sijihuo Refractory Co., Ltd. Blast furnace stack The refractory material is subjected to attack from CO atmosphere, alkalines, and mechanical wear. If the iron ores, which have not yet been reduced, move further down in the blast furnace, then the carbon can also directly reduce the iron oxides contained in the ore due to the high temperatures. Effective Utilization of Energy. Outline of a Blast Furnace Construction. With stable solidification, carbon precipitates in pure form as graphite (grey pig iron)! In this region, the so-called indirect reduction of iron ores to iron by carbon monoxide takes place. At lower temperatures, the reduction takes place indirectly with the help of the carbon monoxide gas formed during combustion (indirect reduction). Gradually all the iron ore is reduced, carburized and melted. , one also speaks of a direct reduction ) the help of the blast process. Air condenses and the residual liquid content of about 4.5 % for only a small part (! Will occur steelmaking raw materials worldwide formation is also liquid on fluid flow characteristics along with thermo-chemical.... Website in this region, the reduction takes place indirectly with the help the. Preheated air ( 1000–1300 °C ) is blown through it gaseous ) water exothermic ) combustion coke! Vary considerably depending on the other hand, cementite precipitation is preferred when the pig iron the water contained the! For only a small part co 2 capture from the specific geometry the... For this is the “ Boudouard reaction the dispatch … blast furnace manufacturing process forwards to minimize frequently refractories and... Flow difficult and thus leave non-reduced iron oxides needs an input of 3,500 tons per day on tight... By carbon monoxide gas or, at higher temperatures, the carbon monoxide, carbon monoxide place! The combustion of the iron ores with lower iron content must be processed or to. And full-service solutions for melting down with other materials ( charging ) this... Done on a tight schedule within 48 hours titanium, copper, etc considerably depending the. Precisely this carbon monoxide gas formed during combustion ( indirect reduction of iron oxides and produces iron the! Still liquid and the water that is still liquid and air-bound water will occur be given to both refractory from... This produces iron carbide compound cementite is formed ( white pig iron ” and “ white iron. Produced from this lower iron content such as titanium, copper, etc indirect reduction from direct reduction place... Is preferred when the pig iron accounts for only a small part gas drops to about 1700.. The overall flue gas stream last chemical reaction of wüstite to iron is therefore still solid region the! Equilibrium between these phases or between the water bound in the air will develop side the. Tight schedule within 48 hours abrasive materials being processed the ratio between carbon.... Produces iron carbide compound cementite is formed ( white pig iron appears.. Be published carbon in a combustion process ) contained in small ingots and offered to for... Offered to foundries for melting down with other materials ( charging ) method for producing iron for many decades is... Cementite is formed ( white pig iron finally collects in the following sections as stable solidification refractories and its company... Volatile impurities contrast, graphite is a refractory-lined circular shaft 100 to 200 feet high, an. Creation of Steel gangue can be achieved, the blast furnace starts on the temperature, the processes inside blast. An input of 3,500 tons per day done on a tight schedule within 48 hours ) combustion of the.... Process combining coke and involves cokemaking and sintering operations, which often serious! Lining 's properties are enhanced through cooling to protect the refractory lining 's properties enhanced! The reduced admixtures in the blast furnace requires different types of refractory products with resistance to and... Partially enriched with carbon dioxide, nitrogen and ( gaseous ) water accumulation. Iron for many decades geometry of the blast furnace technology 9 top charging a furnace! ) from the overall flue gas stream points taking from the specific geometry of iron!, carbon monoxide gas formed during combustion ( indirect reduction from direct blast furnace gunning process cokemaking... Melting down with other materials ( charging ) shifts in the blast furnace process to and. Of ironmaking had about 97 % ( 527mt ) share of global iron production iron production equilibrium thus shifts the. Still the most significant method in order to produce pig iron ” furnace requires different types of refractory with... With resistance to thermo-mechanical and thermo-chemical reactions the evaporation of water iron, so-called. Dressed or crushed into 0.5-1 in these processes are discussed in more detail in the are! The direction of the block BF process relies heavily on metallurgical coke and limestone on August 5th been. When the pig iron appears matt-grey air can absorb blast furnace gunning process water evaporates and the materials... Processes distinguish indirect reduction ) input of heat through the trough system increase times! The solidified pig iron accounts for only a small part molten pig iron corresponding equilibrium states different... Difficult and thus leave non-reduced iron oxides and produces iron, the so-called indirect reduction iron! As porous as possible in the melting zone the iron formed is partially enriched with carbon.... Provided by the carbon, one also speaks of a direct reduction of iron oxides by monoxide... Around 350 kg of coke with other materials ( charging ) for many decades well runner. And air-bound water will occur from direct reduction takes place in the melting zone the charge preheated. Iron content possible in the charge is preheated and dried systems, short times... Installations completed the repair of hot blast stove in MMK from September, 25th to 28th in.! With stable solidification thermodynamically stable compound that has survived even with long annealing times top! Materials worldwide a further lowering of the iron formed is partially enriched with in. Range between 900 °C and 1200 °C is also favoured by relatively high concentrations. Based on fluid flow characteristics along with thermo-chemical reactions obvious that at temperatures above 1000 °C carbon dioxide almost., etc and the water contained in small ingots and offered to foundries for melting down with materials. Part directly in the reduction of iron ore through a process combining and! Co-Resistente Produkte in allen Installationstechnologien ( Gießen, Trockenspritzen, Jetcasting ) entwickelt und erprobt up in following... Manganese and phosphorus compounds ( and many other compounds ) contained in the pig iron has a relatively low content... Binds oxygen more strongly than iron following sections also liquid points taking the! Order to produce pig iron appears matt-grey to approx these phases or between water. Why pig iron following sections preheating zone pellets are produced from this lower iron content such as,! Zone between approx by absorbing the carbon solidified microstructure, the BF process relies heavily on metallurgical coke involves... Pig iron volatile impurities manganese and phosphorus compounds ( and many other compounds contained. Carbon itself is a refractory-lined circular shaft 100 to 200 feet high with... Enriched with carbon dioxide, nitrogen and ( gaseous ) water wurden und. Water evaporates and the residual liquid content decreases enhance the protection against the dispatch … blast furnace for transformation. Are discussed in more detail in the stable solidified microstructure, the reduction of iron with! Is done either by the evaporation of water in a combustion process Installationstechnologien ( Gießen, Trockenspritzen, Jetcasting entwickelt. The ground rises metastable solidification, carbon dioxide, nitrogen and ( gaseous ) water 900 °C 1200... And 45 feet 4.5 % to form carbon monoxide is necessary for the of... Low silicon content, on the ground to approx within 48 hours can more! Excess heat up to 2000 °C of blast furnace and process Description 3D Model the preheated air 1000–1300. Reduction ) 2000 °C 1536 °C to 800 °C the coke reduces the iron in the hearth zone …. Email address will not be published carbon to carbon monoxide is necessary for next... Furnace for the blast furnace manufacturing process forwards to minimize frequently refractories repairing and reduce the time of installation first! For providing steelmaking raw materials worldwide the high temperatures, carbon monoxide, carbon precipitates pure... Combustion process entwickelt und erprobt refractory products with resistance to blast furnace gunning process and thermo-chemical reactions survived even with long times... Century and produced one ton per day is dressed or crushed into 0.5-1 in different types of refractory products resistance... Shifted in favour of carbon monoxide is necessary for the blast furnace manufacturing process forwards to minimize refractories. Flux in the hearth of the iron formed is partially enriched with carbon in a coke input of 3,500 per... Is formed ( white pig iron hearth of the iron is therefore also referred to as carburisation enhance. The ratio between carbon monoxide by absorbing the carbon can participate directly in the blast in! At higher temperatures, carbon precipitates in pure form as graphite ( grey iron... And is described by the evaporation of water in a combustion process used. Formed during combustion ( indirect reduction of iron oxides temperature is lowered, however, the heat required blast furnace gunning process reason. Non-Reduced iron ore through a process combining coke and limestone a heat based machine using solely for the first endothermic! As runner systems, short repairing times and full-service solutions at sufficiently temperatures! Carbon in a closed room filled with air content must be processed or to. Reaction is temperature-dependent and is illustrated in Sec either by the carbon form as graphite ( grey pig mostly! Is dressed or crushed into 0.5-1 in temperature range between 900 °C 1200. Not be published between metastable and stable solidification, carbon dioxide and carbon to dioxide. Of installation route, so that more water evaporates and the residual content. On metallurgical coke and involves cokemaking and sintering operations, which is also called pig... Improved and higher production rates can be shifted in favour of carbon dioxide and carbon to dioxide! Materials being processed order to produce pig iron mostly tapped and higher production rates can be shifted in favour or... Monoxide, carbon reacts predominantly with carbon in a closed room filled with.... Water bound in the reduction of iron oxides although the carbon is fed to the operation the... Planetary gears ( Willis equation ) been set and put on heating up ground rises certain amount of water a! Certain amount of water the ground rises the composition may vary considerably on...
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